Inner nuclear membrane-outer nuclear membrane: inner mitochondrial membrane-outer mitochondrial membrane, inner vesicular membrane and outer vesicular membrane, and when recognized there will be an inner Golgi membrane and an outer Golgi membrane, and an inner RER membrane and an outer RER membrane.  Just a matter of time before someone recognizes how to prove it.  Of course the first two are well established. It makes sense to have an RER which has this polarity.